Molecular control over vitrimer-like mechanics – tuneable dynamic motifs based on the Hammett equation in polyimine materials

Chemistry is cool. WHo would have thought that changing a side group on a polymeric component can change the rheology of the whole network by adjusting the exchange rate kinetics?

Sybren K. Schoustra, Joshua A. Dijksman, Han Zuilhof, Maarten M. J. Smulders — Chemical Science 12, 293–302 (2021)

10.1039/d0sc05458e